The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogenated N-compounds(inorg) / NF3 / Papadimitriou(2013)_253K_184.95-250nm

DATAFILE: NF3_Papadimitriou(2013)_253K_184.95-250nm.txt
NAME: nitrogen trifluoride
FORMULA: NF3
AUTHOR(YEAR): Papadimitriou(2013)
T: 253K
λ: 184.95-250nm
BIBLIOGRAPHY: V.C. Papadimitriou, M.R. McGillen, E.L. Fleming, C.H. Jackman, and J.B. Burkholder, "NF3: UV absorption spectrum temperature dependence and the atmospheric and climate forcing implications", Geophys. Res. Lett. 40, 440-445 (2013); DOI: 10.1002/grl.50120
COMMENTS: Absorption measurements using a 30-W deuterium (D2) or atomic lamp light sources, a jacketed absorption cell with a 90.4 cm path length, a 0.25-m monochromator with a photomultiplier tube detector, and a photodiode detector; spectral resolution ∼1 nm

Data at 5-nm intervals as given in the "Supporting Information" published along with the online version of the paper

Parameterization of the temperature dependence:

log10 (σ(λ,T)) = ∑i Ai λi + (296 – T) ∑i Bi λi

with the following parameters Ai and Bi:

------------------------------------------------
i    Ai       Bi
------------------------------------------------

0  -218.67     0.9261
1   4.03743    -0.0130187
2  -0.0295605    6.096×10-5
3    9.596×10-5    -9.75×10-8
4  -1.3171×10-7      9.76×10-12
5   4.929×10-11

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